The Espeon V (180 / 203) card can be found in the Evolving Skies set.
Recently sold 12 times and based on those sales is worth around £63.50.
Currently, there are 72 open listings for this card on ebay.
This card sells in the range of £52.06 to £74.94, making it quite volatile.
This is a Rare Ultra card.
The fact that it is a V card makes it one of the more valuable cards.